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Lex LuthorThe man who owns Metropolis. Originally a scientist now the corrupt businessman who wants to control the world. He became president, killed thousands, and he was the hardest criminal to ever prove guilty. His history and fights with Supes has made him number one on this list.
BrainiacThe smartest opponent and one of the strongest opponents Superman has ever fought. A living computer who cannot be destroyed and cannot be stopped, but only suppressed by Superman.
General Zod"Come to me Son of Jor-El! Kneel before Zod!"
Banished to the phantom zone by Superman's father, Zod has a serious anger issue built up. He has been freed from the Zone and wants to kill the son of Jor-El.
MetalloA Kyrptonite villain done right. Metallo can disguise himself as a random citizen as long as he covers his metallic body he gained after an accident.
ParasitePerhaps the most unique. An infected working man, whenever he touches someone he drains their energy. If Superman is touched by him, Parasite gains his powers.
DoomsdayHe killed the Man of Steel. He's responsible for one of the biggest events in comic history.
BizarroThe clone of Superman that went wrong, Having all the powers of the Man of Steel but not idea who he really is. He often tries to do good but fails because of his own mentality.
DarkseidAnother very powerful rogue, however i never liked Darkseid very much. However i'm not letting bias sway me from putting him here. From the planet Apokolips he spawns armies and and destroys humans into dust, literally.